Isopropanol → Trichlorocyclopentylsilane

HRID 6449

Reaktionsgleichung

Reaktionsgleichung von HRID 6449
[CH:1]1[CH2:5][CH2:4][CH2:3][CH:2]=1.[Cl:6][SiH:7]([Cl:9])[Cl:8].C(O)(C)C>[H+].[H+].Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl>[CH:1]1([Si:7]([Cl:9])([Cl:8])[Cl:6])[CH2:5][CH2:4][CH2:3][CH2:2]1

Komponenten

5

Edukt 3

HCID 3776IsopropanolHCID 8882CyclopenteneHCID 24811Trichlorosilane

Produkt 1

HCID 84533Trichlorocyclopentylsilane

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 61859Chloroplatinic acidKatalysator

Reaktionsbedingungen

Temperatur
150 °C

Versuchsvorschrift

In a 100 ml autoclave were charged 13.9 g (0.204 mole) of cyclopentene, 25.1 g (0.185 mole) of trichlorosilane and 25 μl of a 0.077 m mole/ml chloroplatinic acid solution in isopropyl alcohol (platinum content 1.92×10-6 mole), which were then stirred at 150° C. for 30 minutes. Cyclopentyl trichlorosilane was obtained quantitatively.

Quellen und Nachweise

ORD-Eintrag
ord-e4a11d3163094ac6b8aeb21c55a2d94d
Quelldatensatz
uspto-grants-1993_09
Patentnummer
US05248803

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