Oxygen → 4-tert-Butylbenzoic acid

HRID 9749

Reaktionsgleichung

Reaktionsgleichung von HRID 9749
[C:1]([C:5]1[CH:10]=[CH:9][C:8]([CH3:11])=[CH:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2].[OH:12]N1C(=O)N(O)C(=O)N(O)[C:14]1=[O:23].[O:24]=O>C([O-])(=O)C.[Co+2].C([O-])(=O)C.C(O)(=O)C>[C:1]([C:5]1[CH:10]=[CH:9][C:8]([C:14]([OH:23])=[O:24])=[CH:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2].[C:1]([C:5]1[CH:6]=[CH:7][C:8]([CH:11]=[O:12])=[CH:9][CH:10]=1)([CH3:4])([CH3:3])[CH3:2]

Komponenten

7

Edukt 3

HCID 977OxygenHCID 73904-tert-ButyltolueneHCID 104197231,3,5-Trihydroxy-1,3,5-triazinane-2,4,6-trione

Produkt 2

HCID 74034-tert-Butylbenzoic acidHCID 703244-tert-Butylbenzaldehyde

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 6277Cobalt diacetateKatalysatorHCID 176Acetic AcidLösungsmittel

Versuchsvorschrift

A mixture of 0.445 g of 4-t-butyltoluene, 0.016 g of hexahydro-1,3,5-trihydroxy-1,3,5-triazine-2,4,6-trione (3% by mole relative to 4-t-butyltoluene), 5 g of acetic acid and 0.004 g of cobalt(II) acetate.4H2O was stirred at 100° C. in an atmosphere of oxygene gas (1 atm=0.1 MPa) for 2 hours. The resulting product in the reaction mixture was analyzed by gas chromatography and was found to yield 4-t-butylbenzoic acid and 4-t-butylbenzaldehyde in 97% and 1% yields, respectively, at 100% conversion of 4-t-butyltoluene.

Quellen und Nachweise

ORD-Eintrag
ord-776d31db73da43fa94d12812791c84cc
Quelldatensatz
uspto-grants-2006_08
Patentnummer
US07091342B2

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