2,2'-Bipyridine → Dimethylamino methacrylate
Reaction equation
[CH3:1][C:2]([C:4]([O:6]CCN(C)C)=[O:5])=[CH2:3].C1C=[C:16](C2N=CC=CC=2)[N:15]=[CH:14]C=1>O.Cl[Cu]>[C:4]([O:6][N:15]([CH3:16])[CH3:14])(=[O:5])[C:2]([CH3:1])=[CH2:3]Participants
5
Reactant 2
Product 1
Reagents, catalysts & solvents 2
Conditions
- Temperature
- 55 °C
Procedure
7 ml DMAEMA (6.531 g; 41.5 mmol), 0.0206 g CuCl (0.208 mmol) and 0.0658 g BiPy (0.421 mmol) were mixed and stirred for 10 minutes. A clear brown solution was formed. To this solution, a solution of 0.1355 g (0.205 mmol) azo-initiator 2 in 7 ml water was added. The temperature of the experiment was maintained at 55° C. The progress of the polymerization is shown in Table 7.
Workup
- customA clear brown solution was formed
Sources & evidence
- ORD record
- ord-c8575b6fb61a403f9badf1d6395bce37
- Source dataset
- uspto-grants-2003_09
- Patent number
- US06624262B2
Reaction notes
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