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Acetic Anhydride → Butyric anhydride

HRID 127178
Notes
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Reaction equation

HRID 127178 reaction equation
C(OC(=O)C)(=O)C.[C:8]([O:15][C:16](=[O:22])[CH2:17][CH2:18][CH2:19][CH2:20]C)(=[O:14])[CH2:9][CH2:10][CH2:11][CH2:12]C>>[C:8]([O:15][C:16](=[O:22])[CH2:17][CH3:18])(=[O:14])[CH2:9][CH3:10].[C:8]([O:15][C:16](=[O:22])[CH2:17][CH2:18][CH3:19])(=[O:14])[CH2:9][CH2:10][CH3:11].[C:8]([O:15][C:16](=[O:22])[CH2:17][CH2:18][CH2:19][CH3:20])(=[O:14])[CH2:9][CH2:10][CH2:11][CH3:12]
ParticipantsProcedureSources & evidenceReaction notes

Participants

5

Reactant 2

HCID 7918Acetic AnhydrideHCID 74918Hexanoic anhydride

Product 3

HCID 7798Butyric anhydrideHCID 31263Propionic anhydrideHCID 74959Valeric anhydride

Procedure

By following in principle the appropriate procedures of Example 4, Parts A and B or Example 5, but substituting other acyl anhydrides for acetic anhydride and caproic anhydride, such as propionic anhydride, butyric anhydride or valeric anhydride, the following compounds are obtained:

Sources & evidence

ORD record
ord-88c0fde5c8134ad889e0112b47692d52
Source dataset
uspto-grants-1981_03
DOI
10.6084/m9.figshare.5104873.v1
Patent number
US04255405

Reaction notes

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On this pageParticipantsProcedureSources & evidenceReaction notes