1,3-Diisopropylbenzene → 2-[3,5-Di(propan-2-yl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

HRID 1491244

Reaction equation

HRID 1491244 reaction equation
CC(C)c1cccc(C(C)C)c1>C1=CCCC=CCC1.C1=CCCC=CCC1.C1CCOC1.CC(C)(C)c1ccnc(-c2cc(C(C)(C)C)ccn2)c1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.C[OH2+].C[OH2+].[Ir].[Ir]>CC(C)c1cc(B2OC(C)(C)C(C)(C)O2)cc(C(C)C)c1

Participants

6

Reactant 1

HCID 74501,3-Diisopropylbenzene

Product 1

HCID 534290492-[3,5-Di(propan-2-yl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolaneYield 83%

Reagents, catalysts & solvents 4

HCID 2733548Bis(pinacolato)diboraneReagentHCID 42491874,4'-Di-tert-butyl-2,2'-bipyridylReagentHCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridiumCatalystHCID 8028TetrahydrofuranSolvent

Conditions

Temperature
25 °C

Sources & evidence

ORD record
ord-bac43139b767409ebec942f4b010d100
Source dataset
Borylation dataset from Roche

Linked notes

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