Potassium Cation → 3,4-Dihydroisoquinoline

HRID 177185

Reaction equation

HRID 177185 reaction equation
[CH2:11]([Cl:12])[Cl:13].[CH2:1]1[NH:2][CH2:3][CH2:4][c:5]2[cH:6][cH:7][cH:8][cH:9][c:10]21.[K+:24].[K+:25].[Na+:27].[Ni+2:40].[OH-:26].[OH2:28].[OH2:29].[OH2:30].[OH2:31].[OH2:32].[OH2:33].[OH2:34].[S:14]([O:15][O:16][S:17]([O-:18])(=[O:19])=[O:20])([O-:21])(=[O:22])=[O:23].[S:35]([O-:36])([O-:37])(=[O:38])=[O:39]>>[CH:1]1=[N:2][CH2:3][CH2:4][c:5]2[cH:6][cH:7][cH:8][cH:9][c:10]21

Participants

10

Reactant 9

HCID 813Potassium Cation2×HCID 923Sodium ionHCID 934Nickel cationHCID 961HydroxideHCID 962Water7×HCID 1117Sulfate IonHCID 6344DichloromethaneHCID 70461,2,3,4-TetrahydroisoquinolineHCID 107879Peroxydisulfate

Product 1

HCID 767053,4-Dihydroisoquinoline

Sources & evidence

ORD record
ord-a8ab8da249e849d2b66a1fbd04479854
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

Linked notes

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