Dimethyl Sulfoxide → Acetic Acid 4-(tert-butyl-diphenyl-silanyloxy)-2-(2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-5-formyl-tetrahydro-furan-3-yl Ester

HRID 186422

Reaction equation

HRID 186422 reaction equation
[C:18]([CH3:19])([CH3:20])([CH3:21])[Si:22]([O:23][CH:24]1[CH:25]([O:39][C:40]([CH3:41])=[O:42])[CH:26]([n:31]2[c:32](=[O:38])[nH:33][c:34](=[O:37])[cH:35][cH:36]2)[O:27][CH:28]1[CH2:29][OH:30])([c:43]1[cH:44][cH:45][cH:46][cH:47][cH:48]1)[c:49]1[cH:50][cH:51][cH:52][cH:53][cH:54]1.[CH3:14][S:15]([CH3:16])=[O:17].[CH3:55][CH2:56][N:57]([CH2:58][CH3:59])[CH2:60][CH3:61].[CH3:65][CH2:66][O:67][C:68](=[O:69])[CH3:70].[Cl:1][C:2]([Cl:3])([Cl:4])[C:5]([O:6][C:7](=[O:8])[C:9]([Cl:10])([Cl:11])[Cl:12])=[O:13].[Cl:62][CH2:63][Cl:64]>>[C:18]([CH3:19])([CH3:20])([CH3:21])[Si:22]([O:23][CH:24]1[CH:25]([O:39][C:40]([CH3:41])=[O:42])[CH:26]([n:31]2[c:32](=[O:38])[nH:33][c:34](=[O:37])[cH:35][cH:36]2)[O:27][CH:28]1[CH:29]=[O:30])([c:43]1[cH:44][cH:45][cH:46][cH:47][cH:48]1)[c:49]1[cH:50][cH:51][cH:52][cH:53][cH:54]1

Participants

7

Reactant 6

HCID 679Dimethyl SulfoxideHCID 6344DichloromethaneHCID 8471TriethylamineHCID 8857Ethyl AcetateHCID 20079Trichloroacetic anhydrideHCID 66774584Acetic Acid 4-(tert-butyl-diphenyl-silanyloxy)-2-(2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-5-hydroxymethyl-tetrahydro-furan-3-yl Ester

Product 1

HCID 86594161Acetic Acid 4-(tert-butyl-diphenyl-silanyloxy)-2-(2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-5-formyl-tetrahydro-furan-3-yl Ester

Sources & evidence

ORD record
ord-412e7a5f8caa4763bef7bee58e439de5
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

Linked notes

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