Magnesium Cation → 5-Bromo-1-(triisopropylsilyl)-1H-indole

HRID 198610

Reaction equation

HRID 198610 reaction equation
[Br:1][c:2]1[cH:3][c:4]2[cH:5][cH:6][nH:7][c:8]2[cH:9][cH:10]1.[CH:13]([CH3:14])([CH3:15])[Si:16]([CH:17]([CH3:18])[CH3:19])([CH:20]([CH3:21])[CH3:22])[Cl:23].[Cl:30][CH2:31][Cl:32].[H-:12].[Mg+2:24].[Na+:11].[O-:25][S:26]([O-:27])(=[O:28])=[O:29].[O:33]=[CH:34][N:35]([CH3:36])[CH3:37].[OH2:38]>>[Br:1][c:2]1[cH:3][c:4]2[cH:5][cH:6][n:7]([Si:16]([CH:13]([CH3:14])[CH3:15])([CH:17]([CH3:18])[CH3:19])[CH:20]([CH3:21])[CH3:22])[c:8]2[cH:9][cH:10]1

Participants

10

Reactant 9

HCID 888Magnesium CationHCID 923Sodium ionHCID 962WaterHCID 1117Sulfate IonHCID 6228DimethylformamideHCID 6344DichloromethaneHCID 249055-BromoindoleHCID 139400Triisopropylsilyl chlorideHCID 166653Hydride

Product 1

HCID 27946525-Bromo-1-(triisopropylsilyl)-1H-indole

Sources & evidence

ORD record
ord-572c699016de423f8a793ed249075ece
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

Linked notes

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