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1,2-Dibromoethane → Methyl (2S)-2-({[(1,1-dimethylethyl)oxy]carbonyl}amino)-5-[4-{[(2-fluorophenyl)methyl]oxy}-3-(methyloxy)phenyl]-5-oxopentanoate

HRID 2264812
Notes
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Reaction equation

HRID 2264812 reaction equation
BrCCBr.[Mg].Br[C:7]1[CH:12]=[CH:11][C:10]([O:13][CH2:14][C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][C:16]=2[F:21])=[C:9]([O:22][CH3:23])[CH:8]=1.FC1C=CC=CC=1COC1C=CC=CC=1OC.[O:41]=[C:42]1[N:46]([C:47]([O:49][C:50]([CH3:53])([CH3:52])[CH3:51])=[O:48])[C@H:45]([C:54]([O:56][CH3:57])=[O:55])[CH2:44][CH2:43]1>C1COCC1.C(OCC)C.C(O)(C)C>[CH3:53][C:50]([O:49][C:47]([NH:46][C@@H:45]([CH2:44][CH2:43][C:42]([C:7]1[CH:12]=[CH:11][C:10]([O:13][CH2:14][C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][C:16]=2[F:21])=[C:9]([O:22][CH3:23])[CH:8]=1)=[O:41])[C:54]([O:56][CH3:57])=[O:55])=[O:48])([CH3:51])[CH3:52]
ParticipantsConditionsProcedureWorkupSources & evidenceReaction notes

Participants

9

Reactant 5

HCID 78391,2-Dibromoethane2×HCID 5462224MagnesiumHCID 108684851-O-tert-butyl 2-O-methyl (2S)-5-oxopyrrolidine-1,2-dicarboxylateHCID 594689134-Bromo-1-{[(2-fluorophenyl)methyl]oxy}-2-(methyloxy)benzeneHCID 667002841-Fluoro-2-({[2-(methyloxy)phenyl]oxy}methyl)benzene

Product 1

HCID 59468971
Methyl (2S)-2-({[(1,1-dimethylethyl)oxy]carbonyl}amino)-5-[4-{[(2-fluorophenyl)methyl]oxy}-3-(methyloxy)phenyl]-5-oxopentanoate
Yield 46.1%

Reagents, catalysts & solvents 3

HCID 3283Diethyl EtherSolventHCID 3776IsopropanolSolventHCID 8028TetrahydrofuranSolvent3×

Conditions

Temperature
-65 °C

Procedure

1,2-Dibromethane (106 uL, 232 mg, 1.233 mmol) was added to a suspension of magnesium (300 mg, 12.33 mmol) in dry THF (3 mL). Then a solution of 4-bromo-1-{[(2-fluorophenyl)methyl]oxy}-2-(methyloxy)benzene (D59, 2.40 g, 8.22 mmol), prepared with analogous procedure to that described hereinabove, in dry THF (17 ml) was added dropwise. The mixture was heated under reflux for 1.5 h. The grignard formation was followed via HPLC (Rt(HPLC, 1-fluoro-2-({[2-(methyloxy)phenyl]oxy}methyl)benzene): 5.59 min, Rt (HPLC, D59): 6.24 min). When the reaction stopped, additional 1,2-dibromethane (0.1 eq) was added. After the grignard formation was complete, the mixture was added dropwise to a solution 1-(1,1-dimethylethyl) 2-methyl (2S)-5-oxo-1,2-pyrrolidinedicarboxylate (D5, 1 g, 4.11 mmol) in dry THF (20 ml) at −65° C. Stirring at −65° C. was continued for 3.5 h. Then isopropanol and diethylether were added, the organic layer was washed with aqueous ammonium chloride solution, dried (Na2SO4) and evaporated. The residue was purified with flash chromatography using a cyclohexanes/ethyl acetate (40% to 100%) gradient to afford the title compound (900 mg, 46%). MS: (ES/+) m/z: 376 [M-BOC+], C25H30FNO7 requires 475; UPLC: 0.84 min, m/z: 476 [MH+], 1H NMR (400 MHz, DMSO-d6) δ (ppm): 7.6 (m, 2H), 7.4 (m, 2H), 7.3-7.2 (m, 4H), 5.2 (s, 2H), 4.1 (m, 1H), 3.8 (s, 3H), 3.6 (s, 3H), 3.2-3.0 (m, 2H), 2.1-2.0 (m, 1H), 1.9 (m, 1H), 1.4 (s, 9H).

Workup

  1. temperatureThe mixture was heated
  2. temperatureunder reflux for 1.5 h
  3. custom5.59 min, Rt (HPLC, D59)
  4. custom6.24 min
  5. washthe organic layer was washed with aqueous ammonium chloride solution
  6. dry with materialdried (Na2SO4)
  7. customevaporated
  8. customThe residue was purified with flash chromatography

Sources & evidence

ORD record
ord-3380eccbc1204f458dc0446a63c69c22
Source dataset
uspto-grants-2010_12
DOI
10.6084/m9.figshare.5104873.v1
Patent number
US07855218B2

Reaction notes

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On this pageParticipantsConditionsProcedureWorkupSources & evidenceReaction notes