Dimethylformamide → 2-(2-(((1,1-Dimethylethyl)dimethylsilyl)oxy)ethyl)-3-(((1,1-dimethylethyl)dimethylsilyl)oxymethyl)-1-azidocyclobutane

HRID 2320008

Reaction equation

[CH3:1][C:2]([CH3:3])([CH3:4])[Si:5]([O:6][CH2:7][CH2:8][CH:9]1[CH:10]([O:22][S:23]([CH3:24])(=[O:25])=[O:26])[CH2:11][CH:12]1[CH2:13][O:14][Si:15]([CH3:16])([CH3:17])[C:18]([CH3:19])([CH3:20])[CH3:21])([CH3:27])[CH3:28].[Li+:32].[N-:29]=[N+:30]=[N-:31].[O:33]=[CH:34][N:35]([CH3:36])[CH3:37]>>[CH3:1][C:2]([CH3:3])([CH3:4])[Si:5]([O:6][CH2:7][CH2:8][CH:9]1[CH:10]([N:29]=[N+:30]=[N-:31])[CH2:11][CH:12]1[CH2:13][O:14][Si:15]([CH3:16])([CH3:17])[C:18]([CH3:19])([CH3:20])[CH3:21])([CH3:27])[CH3:28]

Participants

Reactant 4

HCID 6228Dimethylformamide

HCID 28486Lithium ion

HCID 33558Azide

HCID 197942822-(2-(((1,1-Dimethylethyl)dimethylsilyl)oxy)ethyl)-3-(((1 1-dimethylethyl)dimethylsilyl)oxymethyl)-1-O-methanesulfonylcyclobutanol

Product 1

HCID 197942502-(2-(((1,1-Dimethylethyl)dimethylsilyl)oxy)ethyl)-3-(((1,1-dimethylethyl)dimethylsilyl)oxymethyl)-1-azidocyclobutane

Sources & evidence

ORD record: ord-28ed7c6137344fada878c121640516fd
Source dataset: Training data from https://doi.org/10.1039/C8SC04228D (10/10)
DOI: 10.1039/C8SC04228D

Linked notes

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