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Chlorotrimethylsilane → (E)-4-cyclopentyl-2-(4-(methanesulfonyl)-3-(trifluoromethyl)-phenyl)-but-2-enoic acid methyl ester

HRID 276231
Notes
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Reaction equation

HRID 276231 reaction equation
BrCCBr.C[Si](Cl)(C)C.[CH3:10][O:11][C:12](=[O:22])/[C:13](/I)=[CH:14]\[CH2:15][CH:16]1[CH2:20][CH2:19][CH2:18][CH2:17]1.C1(P(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.Br[C:43]1[CH:48]=[CH:47][C:46]([S:49]([CH3:52])(=[O:51])=[O:50])=[C:45]([C:53]([F:56])([F:55])[F:54])[CH:44]=1.[Cl-].[NH4+]>O1CCCC1.[Zn].C1C=CC(/C=C/C(/C=C/C2C=CC=CC=2)=O)=CC=1.C1C=CC(/C=C/C(/C=C/C2C=CC=CC=2)=O)=CC=1.[Pd]>[CH3:10][O:11][C:12](=[O:22])/[C:13](/[C:43]1[CH:48]=[CH:47][C:46]([S:49]([CH3:52])(=[O:50])=[O:51])=[C:45]([C:53]([F:55])([F:56])[F:54])[CH:44]=1)=[CH:14]/[CH2:15][CH:16]1[CH2:20][CH2:19][CH2:18][CH2:17]1
ParticipantsConditionsProcedureWorkupSources & evidenceReaction notes

Participants

10

Reactant 6

HCID 6397ChlorotrimethylsilaneHCID 78391,2-DibromoethaneHCID 11776TriphenylphosphineHCID 25517Ammonium ChlorideHCID 223152224-Bromo-1-(methylsulfonyl)-2-(trifluoromethyl)benzeneHCID 86584748(E)-4-cyclopentyl-2-iodo-but-2-enoic acid methyl ester

Product 1

HCID 67482895(E)-4-cyclopentyl-2-(4-(methanesulfonyl)-3-(trifluoromethyl)-phenyl)-but-2-enoic acid methyl esterYield 87.1%

Reagents, catalysts & solvents 3

HCID 23994ZincCatalyst6×HCID 6505921(1E,4E)-1,5-diphenylpenta-1,4-dien-3-one; palladiumCatalystHCID 8028TetrahydrofuranSolvent5×

Conditions

Temperature
25 °C

Procedure

A mixture of zinc dust (0.65 g, 10 mmol, Aldrich, −325 mesh) and dry tetrahydrofuran (2 mL) under argon was treated with 1,2-dibromoethane (140 mg, 0.75 mmol). The zinc suspension was then heated with a heat gun to ebullition, allowed to cool, and heated again. This process was repeated three times to make sure the zinc dust was activated. The activated zinc dust suspension was then treated with trimethylsilyl chloride (82 mg, 0.75 mmol), and the suspension was stirred for 15 min at 25° C. The reaction mixture was then treated dropwise with a solution of (E)-4-cyclopentyl-2-iodo-but-2-enoic acid methyl ester (prepared in Example 21, 1.03 g, 3.5 mmol) in dry tetrahydrofuran (1.5 mL) over 3 min. After the addition, the reaction mixture was stirred for 1 h at 40-45° C. and then stirred overnight at 25° C. The reaction mixture was then diluted with dry tetrahydrofuran (3 mL), and the stirring was stopped to allow the excess zinc dust to settle down (˜2 h). In a separate reaction flask, bis(dibenzylideneacetone)palladium(0) (54 mg, 0.1 mmol) and triphenylphosphine (104 mg, 0.4 mmol) in dry tetrahydrofuran (10 mL) was stirred at 25° C. under argon for 10 min and then treated with 4-bromo-1-methanesulfonyl-2-trifluoromethyl-benzene (prepared in Example 12, 0.76 g, 2.5 mmol) and the freshly prepared zinc compound in tetrahydrofuran. The resulting brick red solution was heated at 25° C. for 15 h. The reaction mixture was then poured into a saturated aqueous ammonium chloride solution (50 mL), and the organic compound was extracted into ethyl acetate (2×50 mL). The combined organic extracts were washed with a saturated aqueous sodium chloride solution (1×50 mL), dried over anhydrous magnesium sulfate, filtered, and concentrated in vacuo. Biotage chromatography (FLASH 40M, Silica, 2/1 hexanes/ethyl acetate) afforded (E)-4-cyclopentyl-2-(4-(methanesulfonyl)-3-(trifluoromethyl)-phenyl)-but-2-enoic acid methyl ester (0.85 g, 87%) as a viscous oil: EI-HRMS m/e calcd for C18H21F3O4S (M+) 390.1113, found 390.1113.

Workup

  1. temperatureto cool
  2. temperatureheated again
  3. additionAfter the addition
  4. stirringthe reaction mixture was stirred for 1 h at 40-45° C.
  5. stirringstirred overnight at 25° C
  6. custom(˜2 h)
  7. stirringwas stirred at 25° C. under argon for 10 min
  8. temperatureThe resulting brick red solution was heated at 25° C. for 15 h
  9. extractionthe organic compound was extracted into ethyl acetate (2×50 mL)
  10. washThe combined organic extracts were washed with a saturated aqueous sodium chloride solution (1×50 mL)
  11. dry with materialdried over anhydrous magnesium sulfate
  12. filtrationfiltered
  13. concentrationconcentrated in vacuo

Sources & evidence

ORD record
ord-171a32c167c24738b57c56280012cefd
Source dataset
uspto-grants-2002_03
DOI
10.6084/m9.figshare.5104873.v1
Patent number
US06353111B1

Reaction notes

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On this pageParticipantsConditionsProcedureWorkupSources & evidenceReaction notes