Hydrochloric Acid → 1,3,5-Tris-(p-(dodec-1-yloxycarbonyl)-anilino)-s-triazine

HRID 4159

Reaction equation

[N:1]1[C:8](Cl)=[N:7][C:5](Cl)=[N:4][C:2]=1Cl.[NH2:10][C:11]1[CH:31]=[CH:30][C:14]([C:15]([O:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])=[O:16])=[CH:13][CH:12]=1.Cl>C1(C)C(C)=CC=CC=1>[CH2:18]([O:17][C:15]([C:14]1[CH:13]=[CH:12][C:11]([NH:10][N:1]2[CH2:8][N:7]([NH:10][C:11]3[CH:31]=[CH:30][C:14]([C:15]([O:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])=[O:16])=[CH:13][CH:12]=3)[CH2:5][N:4]([NH:10][C:11]3[CH:12]=[CH:13][C:14]([C:15]([O:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])=[O:16])=[CH:30][CH:31]=3)[CH2:2]2)=[CH:31][CH:30]=1)=[O:16])[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29]

Participants

Conditions

Temperature: 80 °C

Procedure

18.5 g of cyanuric chloride and 92 g of dodecyl p-aminobenzoate in 1,000 ml of xylene were heated at 140° C. until HCl gas was no longer evolved. After 8 hours, the reaction solution was cooled to 80° C., washed twice with saturated sodium bicarbonate solution and once with water, and then cooled to room temperature. The precipitated crystals were filtered off under suction and dried.

Workup

washwashed twice with saturated sodium bicarbonate solution and once with water
temperaturecooled to room temperature
filtrationThe precipitated crystals were filtered off under suction
customdried

Sources & evidence

ORD record: ord-6b8bf34c051a47799634f0478cd59831
Source dataset: uspto-grants-1988_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04724137

Linked notes

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