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Hydrochloric Acid → 1,3,5-Tris-(p-(dodec-1-yloxycarbonyl)-anilino)-s-triazine

HRID 4159
Notes
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Reaction equation

HRID 4159 reaction equation
[N:1]1[C:8](Cl)=[N:7][C:5](Cl)=[N:4][C:2]=1Cl.[NH2:10][C:11]1[CH:31]=[CH:30][C:14]([C:15]([O:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])=[O:16])=[CH:13][CH:12]=1.Cl>C1(C)C(C)=CC=CC=1>[CH2:18]([O:17][C:15]([C:14]1[CH:13]=[CH:12][C:11]([NH:10][N:1]2[CH2:8][N:7]([NH:10][C:11]3[CH:31]=[CH:30][C:14]([C:15]([O:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])=[O:16])=[CH:13][CH:12]=3)[CH2:5][N:4]([NH:10][C:11]3[CH:12]=[CH:13][C:14]([C:15]([O:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])=[O:16])=[CH:30][CH:31]=3)[CH2:2]2)=[CH:31][CH:30]=1)=[O:16])[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29]
ParticipantsConditionsProcedureWorkupSources & evidenceReaction notes

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 7954Cyanuric chlorideHCID 328885Dodecyl 4-aminobenzoate

Product 1

HCID 201527391,3,5-Tris-(p-(dodec-1-yloxycarbonyl)-anilino)-s-triazine

Reagents, catalysts & solvents 1

HCID 7237O-XyleneSolvent

Conditions

Temperature
80 °C

Procedure

18.5 g of cyanuric chloride and 92 g of dodecyl p-aminobenzoate in 1,000 ml of xylene were heated at 140° C. until HCl gas was no longer evolved. After 8 hours, the reaction solution was cooled to 80° C., washed twice with saturated sodium bicarbonate solution and once with water, and then cooled to room temperature. The precipitated crystals were filtered off under suction and dried.

Workup

  1. washwashed twice with saturated sodium bicarbonate solution and once with water
  2. temperaturecooled to room temperature
  3. filtrationThe precipitated crystals were filtered off under suction
  4. customdried

Sources & evidence

ORD record
ord-6b8bf34c051a47799634f0478cd59831
Source dataset
uspto-grants-1988_02
DOI
10.6084/m9.figshare.5104873.v1
Patent number
US04724137

Reaction notes

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On this pageParticipantsConditionsProcedureWorkupSources & evidenceReaction notes