Allyl methacrylate → 2-Propenoic acid, 2-methyl-, 3-[1,3,3,3-tetramethyl-1-[(trimethylsilyl)oxy]-1-disiloxanyl]propyl ester

HRID 704842

Reaction equation

[C:1]([O:6][CH2:7][CH:8]=[CH2:9])(=[O:5])[C:2]([CH3:4])=[CH2:3].[CH3:10][Si:11]([CH3:21])([CH3:20])[O:12][SiH:13]([CH3:19])[O:14][Si:15]([CH3:18])([CH3:17])[CH3:16].[SiH4]>[H+].[H+].Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl.C(O)(C)C>[CH3:10][Si:11]([CH3:20])([CH3:21])[O:12][Si:13]([CH3:19])([CH2:9][CH2:8][CH2:7][O:6][C:1](=[O:5])[C:2]([CH3:4])=[CH2:3])[O:14][Si:15]([CH3:18])([CH3:17])[CH3:16]

Participants

Conditions

Temperature: 70 °C

Procedure

Into 63 parts of allyl methacrylate admixed with 0.04 part of chloroplatinic acid in the form of an isopropyl alcohol solution and heated at 60° 70° C. were added dropwise gradually 111 parts of 1,1,1,3,5,5,5-heptamethyl trisiloxane and, after completion of the dropwise addition of the silane compound, the mixture was heated at 90° C. for further 2 hours to complete the reaction. Thereafter, the reaction mixture was distilled under reduced pressure to be freed from the unreacted reactants and then filtered to give 1,1,1,3,5,5,5- heptamethyl-3-(3-methacryloxypropyl) trisiloxane, which is referred to as the compound B-1 hereinbelow, in a yield of 165 parts corresponding to 95% of the theoretical yield.

Workup

temperaturethe mixture was heated at 90° C. for further 2 hours
customthe reaction
distillationThereafter, the reaction mixture was distilled under reduced pressure
filtrationfiltered

Sources & evidence

ORD record: ord-3da27bda073541c391b39d95b23b01c1
Source dataset: uspto-grants-1991_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04988788

Linked notes

Loading…