2,3-Dinitrophenol → Sodium dinitrophenolate

HRID 874859

Reaction equation

HRID 874859 reaction equation
[N+:1]([C:4]1[C:5]([N+:11]([O-:13])=[O:12])=[C:6]([OH:10])[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2].[H-].[Na+:15]>C1COCC1>[N+:1]([C:4]1[C:5]([N+:11]([O-:13])=[O:12])=[C:6]([O-:10])[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2].[Na+:15]

Participants

4

Reactant 2

HCID 61912,3-DinitrophenolHCID 24758Sodium hydride

Product 1

HCID 86649331Sodium dinitrophenolate

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

The anhydrous dinitrophenol (10.0 g, 54.3 mmol) was dissolved in anhydrous THF (300 mL) and then NaH(1.30 g, 54.3 mmol) was added slowly. After the solution was stirred for 3 hrs, solvent was removed under the reduced pressure to obtain 100 mol % sodium dinitrophenolate.

Workup

  1. customsolvent was removed under the reduced pressure

Sources & evidence

ORD record
ord-d8af27706dff4fbb87b4281472467d2c
Source dataset
uspto-grants-2015_03
Patent number
US08981043B2

Linked notes

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