2,3-Dinitrophenol → Sodium dinitrophenolate
Reaction equation
[N+:1]([C:4]1[C:5]([N+:11]([O-:13])=[O:12])=[C:6]([OH:10])[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2].[H-].[Na+:15]>C1COCC1>[N+:1]([C:4]1[C:5]([N+:11]([O-:13])=[O:12])=[C:6]([O-:10])[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2].[Na+:15]Participants
4
Reactant 2
Product 1
Reagents, catalysts & solvents 1
Procedure
The anhydrous dinitrophenol (10.0 g, 54.3 mmol) was dissolved in anhydrous THF (300 mL) and then NaH(1.30 g, 54.3 mmol) was added slowly. After the solution was stirred for 3 hrs, solvent was removed under the reduced pressure to obtain 100 mol % sodium dinitrophenolate.
Workup
- customsolvent was removed under the reduced pressure
Sources & evidence
- ORD record
- ord-d8af27706dff4fbb87b4281472467d2c
- Source dataset
- uspto-grants-2015_03
- Patent number
- US08981043B2
Reaction notes
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