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Acetone → Glyceraldehyde

HRID 889680
Notes
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Reaction equation

HRID 889680 reaction equation
CC([OH:4])C.CC(C)=[O:7].[OH:9][CH2:10][CH:11]([CH2:13][OH:14])[OH:12]>>[O:9]=[CH:10][CH:11]([CH2:13][OH:14])[OH:12].[OH:4][CH:13]([OH:14])[C:11](=[O:12])[CH3:10].[C:10]([OH:7])(=[O:9])[CH:11]([CH2:13][OH:14])[OH:12]
ParticipantsProcedureSources & evidenceReaction notes

Participants

6

Reactant 3

HCID 180AcetoneHCID 753GlycerolHCID 3776Isopropanol

Product 3

HCID 751GlyceraldehydeHCID 752Glyceric acidHCID 131809821,1-Dihydroxypropan-2-one

Procedure

Oxidation catalysts of the present invention may be used for liquid phase oxidation reactions. Examples of such reactions include the oxidation of alcohols and polyols to form aldehydes, ketones, and acids (e.g., the oxidation of 2-propanol to form acetone, and the oxidation of glycerol to form glyceraldehyde, dihydroxyacetone, or glyceric acid); the oxidation of aldehydes to form acids (e.g., the oxidation of formaldehyde to form formic acid, and the oxidation of furfural to form 2-furan carboxylic acid); the oxidation of tertiary amines to form secondary amines (e.g., the oxidation of nitrilotriacetic acid (NTA) to form iminodiacetic acid (IDA)); the oxidation of secondary amines to form primary amines (e.g., the oxidation of IDA to form glycine); and the oxidation of various acids (e.g., formic acid or acetic acid) to form carbon dioxide and water.

Sources & evidence

ORD record
ord-c760a617106848b69b734e30ec685569
Source dataset
uspto-grants-2012_08
DOI
10.6084/m9.figshare.5104873.v1
Patent number
US08252953B2

Reaction notes

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On this pageParticipantsProcedureSources & evidenceReaction notes