Azobisisobutyronitrile → HCID 86619238、化合物

HRID 1010510ノート

反応式

HRID 1010510 の反応式
[C:1]([OH:5])(=[O:4])[CH:2]=[CH2:3].[C:6]([O:11][CH2:12][C:13]([F:21])([F:20])[CH:14]([F:19])[C:15]([F:18])([F:17])[F:16])(=[O:10])[C:7]([CH3:9])=[CH2:8].[C:22]([O:26]CCCC)(=[O:25])[CH:23]=[CH2:24].[CH2:31]=[CH:32][C:33]1[CH:38]=[CH:37][CH:36]=[CH:35][CH:34]=1.N(C(C)(C)C#N)=NC(C)(C)C#N.C(OC(C)COC)(=O)C>>[C:1]([OH:5])(=[O:4])[CH:2]=[CH2:3].[C:6]([O:11][CH2:12][C:13]([F:20])([F:21])[CH:14]([F:19])[C:15]([F:17])([F:18])[F:16])(=[O:10])[C:7]([CH3:9])=[CH2:8].[C:22]([O:26][C:33]([CH3:32])([CH3:34])[CH3:38])(=[O:25])[CH:23]=[CH2:24].[CH2:31]=[CH:32][C:33]1[CH:38]=[CH:37][CH:36]=[CH:35][CH:34]=1

参加物

7

反応物 6

HCID 6547AzobisisobutyronitrileHCID 6581Acrylic AcidHCID 7501StyreneHCID 7946Propylene glycol methyl ether acetateHCID 8846Butyl AcrylateHCID 5497722,2,3,4,4,4-Hexafluorobutyl methacrylate

生成物 1

HCID 86619238HCID 86619238、化合物収率 82%

実験手順

Acrylic acid (4.2 g), 2,2,3,4,4,4-hexafluorobutyl methacrylate (14 g), t -butyl acrylate (14 g) and styrene (8.26 g) were mixed with azobisisobutyronitrile (AIBN) (4 g) as a polymerization initiator and propyleneglycol methyl ether acetate (PGMEA) (145 g) as a polymerization solvent. The resulting mixture was reacted at approximately 67° C. for approximately 12 hours, and precipitated in normal hexane and dehydrated to obtain an organic polymer compound with yield of approximately 82% (see FIG. 3).

後処理

  1. customThe resulting mixture was reacted at approximately 67° C. for approximately 12 hours
  2. customprecipitated in normal hexane
  3. customto obtain an organic polymer compound with yield of approximately 82% (see FIG. 3)

出典と根拠

ORDレコード
ord-80be31d6cfef40cebd367bf4287b09b7
出典データセット
uspto-grants-2011_07
特許番号
US07977035B2

反応ノート

読み込み中…