Water → 1,1'-(Dithiodicarbonothioyl)bis(4-methylpiperazine)

HRID 1032001

反応式

HRID 1032001 の反応式
[CH3:1][N:2]1[CH2:7][CH2:6][NH:5][CH2:4][CH2:3]1.O.[OH-].[Na+].[C:11](=[S:13])=[S:12]>[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[K+].[K+].[K+].[Fe+3]>[CH3:1][N:2]1[CH2:7][CH2:6][N:5]([C:11]([S:13][S:13][C:11]([N:5]2[CH2:6][CH2:7][N:2]([CH3:1])[CH2:3][CH2:4]2)=[S:12])=[S:12])[CH2:4][CH2:3]1

参加物

6

反応物 4

HCID 962WaterHCID 6348Carbon DisulfideHCID 14798Sodium HydroxideHCID 531671-Methylpiperazine

生成物 1

HCID 300541,1'-(Dithiodicarbonothioyl)bis(4-methylpiperazine)

試薬・触媒・溶媒 1

HCID 26250Potassium ferricyanide触媒

実験手順

5 parts of N-methylpiperazine are reacted in 100 parts of water with 2 parts of sodium hydroxide and 4.2 parts of carbon disulfide and oxidized with 16.5 parts of potassium hexacyanoferrate(III). Obtained are 8.6 parts of the compound with 41.1% C, 6.5% H, and 15.7% N (calculated: 41.1% C, 6.3% H, 16.0% N, 36.6% S).

後処理

  1. customObtained

出典と根拠

ORDレコード
ord-d62a17d3cd924e699fc26ff9dad7e5fb
出典データセット
uspto-grants-1990_09
特許番号
US04956433

関連ノート

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