Ethyl sulfide → Diethylthioether Silver Nitrate

To a 100 ml round bottom flask was sequentially added 10 mmol (1.69 g) of silver nitrate and 20 ml of acetonitrile, followed by stirring at room temperature for 5 minutes. Next, 10 mmol (0.90 g, 1.08 ml) of diethylthioether was dropwise added to the flask by means of a syringe over 10 seconds and stirred at room temperature. After stirring for 30 minutes, the reaction mixture was warmed to 50° C. and further stirred for 30 minutes. Following cooling to room temperature, the reaction mixture was filtered through a microfilter and evaporated under vacuum to produce a pale ivory solid matter. 1H-NMR result in CD3CN is as follows: 1.34 (t, 7.36 Hz, 6H), 2.76(q, 7.36 Hz, 4H).

1. customTo a 100 ml round bottom flask was sequentially added
2. stirringstirred at room temperature
3. stirringAfter stirring for 30 minutes
4. temperaturethe reaction mixture was warmed to 50° C.
5. stirringfurther stirred for 30 minutes
6. temperatureFollowing cooling to room temperature
7. filtrationthe reaction mixture was filtered through a microfilter
8. customevaporated under vacuum
9. customto produce a pale ivory solid matter
10. custom1H-NMR result in CD3CN

ORDレコード

ord-bff01c618220429d988283336dd2d59e

出典データセット

uspto-grants-2005_11

DOI

10.6084/m9.figshare.5104873.v1

特許番号

US06965045B2