Sodium Hydroxide → Perilla alcohol

HRID 1076764

反応式

HRID 1076764 の反応式
[CH3:1][C:2]([CH:4]1[CH2:9][CH:8]=[C:7]([CH2:10][O:11]C(C)=O)[CH2:6][CH2:5]1)=[CH2:3].[OH-].[Na+]>>[CH3:3][C:2]([C@@H:4]1[CH2:5][CH:6]=[C:7]([CH2:10][OH:11])[CH2:8][CH2:9]1)=[CH2:1]

参加物

3

反応物 2

HCID 14798Sodium HydroxideHCID 61780Perillyl acetate

生成物 1

HCID 369312Perilla alcohol収率 97.7%

実験手順

Perillyl acetate (196 g.) derived from either of the examples mentioned and 30% aqueous sodium hydroxide (60 g.) were refluxed gently with stirring for 4 hours. The oil layer was separated and distilled under reduced pressure to give perillyl alcohol (150 g.) b.P. 80°/0.7 mm., αD20 + 102.5.

後処理

  1. customThe oil layer was separated
  2. distillationdistilled under reduced pressure

出典と根拠

ORDレコード
ord-39ae34768f2747dca013ecfce2e00257
出典データセット
uspto-grants-1976_05
特許番号
US03957856

関連ノート

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