Carbon Disulfide → HCID 13561953、化合物

HRID 1249052

反応式

HRID 1249052 の反応式
[CH2:1]1[C:13]2[NH:12][C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH2:4][C@H:3]([C:14]([OH:16])=[O:15])[NH:2]1.[OH-].[K+].[CH2:19](Cl)[C:20]1[O:24][CH:23]=[CH:22][CH:21]=1.C(O)C1OC=CC=1.S(Cl)(Cl)=O.[C:37](=[S:39])=[S:38]>N1C=CC=CC=1.C(O)C>[CH2:19]([S:39][C:37]([N:2]1[C@@H:3]([C:14]([OH:16])=[O:15])[CH2:4][C:5]2[C:6]3[C:11](=[CH:10][CH:9]=[CH:8][CH:7]=3)[NH:12][C:13]=2[CH2:1]1)=[S:38])[C:20]1[O:24][CH:23]=[CH:22][CH:21]=1

参加物

9

反応物 6

HCID 6348Carbon DisulfideHCID 7361Furfuryl AlcoholHCID 14797Potassium HydroxideHCID 24386Thionyl ChlorideHCID 2195202-(Chloromethyl)furanHCID 675102D-1,2,3,4-Tetrahydronorharman-3-carboxylic acid

生成物 1

HCID 13561953HCID 13561953、化合物

試薬・触媒・溶媒 2

HCID 702Ethanol溶媒HCID 1049Pyridine溶媒

実験手順

In the same manner as descsribed in Example 32, (3R)-1,2,3,4-tetrahydro-β-carboline-3-carboxylic acid (8.65 g), KOH (4.67 g), carbon disulfide (2.43 ml), 75% ethanol (120 ml) and furfuryl chloride which is prepared from furfuryl alcohol (9.24 g), thionyl chloride (12.34 g) and pyridine (8.94 g) are reacted and treated to give the title compound (2.31 g) as pale yellow powder.

後処理

  1. customare reacted
  2. additiontreated

出典と根拠

ORDレコード
ord-4d04b1f0650b4fee9de48418bb2f4bae
出典データセット
uspto-grants-1986_12
特許番号
US04628057

関連ノート

読み込み中…