Allyl Alcohol → HCID 23186913、化合物

HRID 1258987

反応式

HRID 1258987 の反応式
C(O)C=C.BrCC1C=CC(C(O)=O)=CC=1.[H-].[Na+].[CH2:18]([O:22][CH2:23][C:24]1[CH:32]=[CH:31][C:27]([C:28]([OH:30])=[O:29])=[CH:26][CH:25]=1)[CH2:19][CH:20]=C>>[CH2:18]([O:22][CH2:23][C:24]1[CH:32]=[CH:31][C:27]([C:28]([OH:30])=[O:29])=[CH:26][CH:25]=1)[CH:19]=[CH2:20]

参加物

5

反応物 4

HCID 7858Allyl AlcoholHCID 225994-(Bromomethyl)benzoic acidHCID 24758Sodium hydrideHCID 221369964-But-3-enyloxymethyl-benzoic acid

生成物 1

HCID 23186913HCID 23186913、化合物

実験手順

The reaction of allyl alcohol and 4-Bromomethyl-benzoic acid in the presence of sodium hydride was performed as described for Compound 33 to give 4-Allyloxymethyl-benzoic acid as white powder. 1H-NMR (400 MHz, d6-DMSO): 7.91 (d, J=8.3, 2 arom. H); 7.42 (d, J=8.3, 2 arom.H); 5.90 (m, —CHCH2); 5.30, 5.18 (2 d-like, —CH═CH2); 4.54 (s, —OCH2—C6H4); 4.01 (2 d-like, CH2═CHCH2O). 13C-NMR (100 MHz, d6-DMSO): 161.18 (—C═O); 143.48; 134.97; 129.95; 129.31 (2 arom.C); 127.11 (2 arom.C); 116.63; 70.64 (2 C).

出典と根拠

ORDレコード
ord-03bb24bae0054ee5940aba84f32d59ef
出典データセット
uspto-grants-2013_06
特許番号
US08466199B2

関連ノート

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