a Farnesol → 3,7,11-Trimethyldodeca-2,6,10-trienyl 2-phenylacetate

HRID 129032

反応式

HRID 129032 の反応式
[OH:1][CH2:2][CH:3]=[C:4]([CH2:6][CH2:7][CH:8]=[C:9]([CH2:11][CH2:12][CH:13]=[C:14]([CH3:16])[CH3:15])[CH3:10])[CH3:5].[C:17]1([CH2:23][C:24](Cl)=[O:25])[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1>>[C:17]1([CH2:23][C:24]([O:1][CH2:2][CH:3]=[C:4]([CH2:6][CH2:7][CH:8]=[C:9]([CH2:11][CH2:12][CH:13]=[C:14]([CH3:16])[CH3:15])[CH3:10])[CH3:5])=[O:25])[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1

参加物

3

反応物 2

HCID 3327a FarnesolHCID 7679Phenylacetyl chloride

生成物 1

HCID 542166103,7,11-Trimethyldodeca-2,6,10-trienyl 2-phenylacetate収率 54%

実験手順

A mixture of farnesol (440 mg, 2 mmol) and phenylacetyl chloride (584 mg, 7.8 mmol) was refluxed for 2.5 hours. Extraction with hexane, and purification yielded 368 mg (yield: 54%) of oil having the following physical properties.

後処理

  1. temperaturewas refluxed for 2.5 hours
  2. extractionExtraction
  3. customwith hexane, and purification

出典と根拠

ORDレコード
ord-1d1526befd3a4af7a497eab7cf9d512e
出典データセット
uspto-grants-1995_11
特許番号
US05466718

関連ノート

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