Benzene → 4-Vinylpyridine styrene

HRID 1389520

反応式

HRID 1389520 の反応式
[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[N:9](C(C)(C)C#N)=NC(C)(C)C#N.C1C=CC=CC=1.C(C1C=CC=CN=1)=C>CCCCCC>[CH:2]([C:3]1[CH:8]=[CH:7][N:9]=[CH:5][CH:4]=1)=[CH2:1].[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

参加物

6

反応物 4

HCID 241BenzeneHCID 6547AzobisisobutyronitrileHCID 7501StyreneHCID 75212-Vinylpyridine

生成物 1

HCID 126664554-Vinylpyridine styrene収率 20%

試薬・触媒・溶媒 1

HCID 8058Hexane溶媒

実験手順

In a 200 ml three necked flask were charged 21 g of 4-vinylpyridine, 21 g of styrene and 0.1 g of azobisisobutyronitrile and 90 ml of benzene. The mixture was polymerized at 80° C. for 6 hrs under a nitrogen atmosphere. The reaction liquid was poured into a large amount of n-hexane to thereby obtain white precipitates. After filtering and drying, a white powder was obtained. The molar fraction of vinylpyridine in the polymer was 0.57 and the yield was 20%.

後処理

  1. customThe mixture was polymerized at 80° C. for 6 hrs under a nitrogen atmosphere
  2. customThe reaction liquid
  3. customto thereby obtain white precipitates
  4. filtrationAfter filtering
  5. customdrying
  6. customa white powder was obtained

出典と根拠

ORDレコード
ord-2fc78f28946d42f0a1e6089859ad9551
出典データセット
uspto-grants-1981_01
特許番号
US04245027

関連ノート

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