3-Methoxybenzaldehyde → 5-Methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-YL)benzaldehyde

HRID 1490615ノート

反応式

HRID 1490615 の反応式
COc1cccc(C=O)c1>C1=CCCC=CCC1.C1=CCCC=CCC1.C1CCOC1.CC(C)(C)N.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.CC1(C)OBOC1(C)C.C[OH2+].C[OH2+].Nc1cccc2cccnc12.[Ir].[Ir]>COc1ccc(B2OC(C)(C)C(C)(C)O2)c(C=O)c1

参加物

8

反応物 1

HCID 115693-Methoxybenzaldehyde

生成物 1

HCID 716694775-Methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-YL)benzaldehyde収率 88%

試薬・触媒・溶媒 6

HCID 6385Tert-Butylamine試薬HCID 113598-Aminoquinoline試薬HCID 2733548Bis(pinacolato)diborane試薬HCID 27347684,4,5,5-Tetramethyl[1,3,2]dioxaborolane試薬HCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridium触媒HCID 8028Tetrahydrofuran溶媒

反応条件

温度
90 °C

出典と根拠

ORDレコード
ord-7eee4baf36dc47659de502ddc45543eb
出典データセット
Borylation dataset from Roche

反応ノート

読み込み中…