4-Chlorobenzaldehyde 2,2-dimethylhydrazone → HCID 178484938、化合物

HRID 1491502ノート

反応式

HRID 1491502 の反応式
CN(C)N=Cc1ccc(Cl)cc1>C(=NN(Cc1ccccc1)Cc1ccccc1)c1ccccn1.C1=CCCC=CCC1.C1=CCCC=CCC1.C1CCOC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.CC1(C)OBOC1(C)C.C[OH2+].C[OH2+].[Ir].[Ir]>CN(C)N=Cc1ccc(Cl)cc1B1OC(C)(C)C(C)(C)O1

参加物

7

反応物 1

HCID 2112214-Chlorobenzaldehyde 2,2-dimethylhydrazone

生成物 1

HCID 178484938HCID 178484938、化合物収率 73%

試薬・触媒・溶媒 5

HCID 2733548Bis(pinacolato)diborane試薬HCID 27347684,4,5,5-Tetramethyl[1,3,2]dioxaborolane試薬HCID 67601456N,N-Dibenzyl-N'-(pyridin-2-ylmethylene)hydrazine試薬HCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridium触媒HCID 8028Tetrahydrofuran溶媒

反応条件

温度
80 °C

実験手順

Following the general procedure, column chromatography in neutral alumina (EtOAc/n-hexane 1:10) afforded 11g (112 mg, 73 %).

出典と根拠

ORDレコード
ord-4f76430a1a884af5b1fb0714cab85713
出典データセット
Borylation dataset from Roche

反応ノート

読み込み中…