Hydrochloric Acid → Acrylamide

HRID 1606748

反応式

HRID 1606748 の反応式
[CH2:1]=[CH:2][S:3]([O-:6])(=[O:5])=[O:4].[Na+].N([O-])=O.[Na+].NC(N)=O.Cl.[C:17]([NH2:21])(=[O:20])[CH:18]=[CH2:19].C(#N)C=C.S(S([O-])=O)([O-])(=O)=O.[Na+].[Na+].S(OOS([O-])(=O)=O)([O-])(=O)=O.[NH4+].[NH4+]>O=O.C(O)C.O>[C:17](#[N:21])[CH:18]=[CH2:19].[C:17]([NH2:21])(=[O:20])[CH:18]=[CH2:19].[CH2:1]=[CH:2][S:3]([OH:6])(=[O:5])=[O:4]

参加物

14

反応物 8

HCID 313Hydrochloric AcidHCID 1176UreaHCID 6579AcrylamideHCID 7855AcrylonitrileHCID 62648Ammonium PersulfateHCID 656671Sodium PyrosulfiteHCID 3270262Sodium vinylsulfonateHCID 23668193Sodium Nitrite

生成物 3

HCID 6579AcrylamideHCID 7855AcrylonitrileHCID 62474Vinylsulfonic acid

試薬・触媒・溶媒 3

HCID 702Ethanol溶媒HCID 962Water溶媒HCID 977Oxygen溶媒

実験手順

A water-soluble copolymer of acrylonitrile, acrylamide and ethylene sulfonic acid was prepared in the following way: 57.5 g of an aqueous 47% solution of sodium ethylene sulfonate, stabilized against polymerization by 0.2% sodium nitrite, was destabilized by adding 3 g urea and acidified with concentrated hydrochloric acid to pH 2. The developing gases were repeatedly drawn off. 7.1 g Acrylamide and 13.6 ml acrylonitrile were added and the monomer mixture was dissolved in 76 ml of oxygen-free water. 1 ml of a 5% sodium pyrosulfite solution and the same amount of ammonium persulfate were stirred in, and the somewhat turbid solution was left standing under carbon dioxide at room temperature for 24 hours. The viscous solution thus obtained was poured into 2 liters of anhydrous ethanol. The white coagulate was purified by dissolving it in water and again precipitating it in anhydrous ethanol, broken to small pieces and dried at 70° C.

後処理

  1. waitwas left
  2. customThe viscous solution thus obtained
  3. customThe white coagulate was purified
  4. dissolutionby dissolving it in water
  5. customagain precipitating it in anhydrous ethanol
  6. customdried at 70° C.

出典と根拠

ORDレコード
ord-035102b7b2114125aea921d27431fc01
出典データセット
uspto-grants-1976_04
特許番号
US03953545

関連ノート

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