Water → HCID 12770097、化合物

HRID 1659445

反応式

HRID 1659445 の反応式
CS[S:3][CH3:4].[CH:5]1[CH2:10][CH2:9][CH2:8][CH2:7][CH:6]=1.[OH2:11].[C:12](#[N:14])[CH3:13]>F[B-](F)(F)F.C([N+](CCCC)(CCCC)CCCC)CCC.[Pt]>[C:12]([NH:14][CH:5]1[CH2:10][CH2:9][CH2:8][CH2:7][CH:6]1[S:3][CH3:4])(=[O:11])[CH3:13]

参加物

7

反応物 4

HCID 962WaterHCID 6342AcetonitrileHCID 8079CyclohexeneHCID 12232Dimethyl Disulfide

生成物 1

HCID 12770097HCID 12770097、化合物

試薬・触媒・溶媒 2

HCID 23939Platinum触媒HCID 67932Tetrabutylammonium Tetrafluoroborate触媒

実験手順

A mixture of dimethyldisulphide (96 mg) in acetonitrile containing cyclohexene (405 mg) was placed in a conventional H-type electrolytic cell. The cell was provided with a number 4 sintered glass frit as divider and with 1 sq. cm. platinum mesh cathode and anode. The potential measurement was made with respect to a Ag/Ag+ (0.01 M) reference electrode. Tetra-n-butyl ammonium fluoroborate (0.1 M) was added as electrolyte. A constant potential of 1.20 volts was maintained at the anode with a potentiostat until 2 coulomb equivalents of charge per mole of disulphide had been passed. Water was then added to the anolyte and the aqueous phase extracted with diethyl ether to yield 116 mg of 2-acetamido 1-methylthio cyclohexane. Mass Spec. m/e 187 (parent ion). I.R. 3290 & 1650 cm-1.

後処理

  1. customThe cell was provided with a number 4 sintered glass frit as divider and with 1 sq. cm
  2. temperatureA constant potential of 1.20 volts was maintained at the anode with a potentiostat until 2 coulomb equivalents
  3. extractionthe aqueous phase extracted with diethyl ether

出典と根拠

ORDレコード
ord-cca45905f75849ea9cac28a2fe69eaf8
出典データセット
uspto-grants-1981_12
特許番号
US04304642

関連ノート

読み込み中…