Phenacyl bromide → Phenacyl thiocyanate

HRID 1660671ノート

反応式

HRID 1660671 の反応式
Br[CH2:2][C:3]([C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)=[O:4].[SiH4].[S-:12][C:13]#[N:14].[Na+]>C(O)C>[S:12]([CH2:2][C:3]([C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)=[O:4])[C:13]#[N:14]

参加物

5

反応物 3

HCID 6259Phenacyl bromideHCID 23953SilaneHCID 516871Sodium thiocyanate

生成物 1

HCID 219693Phenacyl thiocyanate

試薬・触媒・溶媒 1

HCID 702Ethanol溶媒

実験手順

Bromoacetophenone-modified aminopropylsilylated glass surfaces (2.5×7.5 cm; Sigma, Silane-Prep™, S4651) (see Example 13) were coated with a 0.1M solution of sodium thiocyanate in ethanol and incubated for five hours at 50° C. The glass surfaces thus treated were then washed five times using respectively 30 mL of ethanol for 3 minutes each at room temperature. After washing three times for three minutes each using respectively 30 mL of DCM at room temperature, the glass surfaces were dried and stored at 4° C. until further use.

後処理

  1. additionThe glass surfaces thus treated
  2. washwere then washed five times
  3. customfor 3 minutes
  4. customat room temperature
  5. washAfter washing three times for three minutes each using respectively 30 mL of DCM at room temperature
  6. customthe glass surfaces were dried
  7. customstored at 4° C. until further use

出典と根拠

ORDレコード
ord-6c69b8cd2f5d46608e9d805dbc1a368d
出典データセット
uspto-grants-2011_10
特許番号
US08029979B2

反応ノート

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