Chlorotrimethylsilane → HCID 19705234、化合物
反応式
[Cl:1][C:2]1[CH:3]=[C:4]([C:8](O)([CH3:10])[CH3:9])[CH:5]=[CH:6][CH:7]=1.[Br-:12].[Li+].C[Si](Cl)(C)C>C(#N)C>[Br:12][C:8]([C:4]1[CH:5]=[CH:6][CH:7]=[C:2]([Cl:1])[CH:3]=1)([CH3:10])[CH3:9]参加物
5
実験手順
This compound is prepared in a manner analogous to that of Step A of Example 5, using 8.5 grams (0.05 mole) of 2-(3-chlorophenyl)propan-2-ol, 8.7 grams (0.1 mole) of lithium bromide, and 13.5 grams (0.125 mole) of trimethylsilyl chloride in 100 mL of acetonitrile, yielding 2-bromo-2-(3-chlorophenyl)propane.
後処理
- customThis compound is prepared in a manner analogous to that of Step A of Example 5
出典と根拠
- ORDレコード
- ord-51a116ca6e50457e80d725a723cc4358
- 出典データセット
- uspto-grants-1996_07
- 特許番号
- US05536725
反応ノート
読み込み中…