Nitric Acid → Tetradecanoic acid, cadmium salt (2:1)

HRID 1960234

反応式

HRID 1960234 の反応式
[S].[C:2]([OH:21])(=[O:20])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9]/[CH:10]=[CH:11]\[CH2:12][CH2:13][CH2:14][CH2:15]CCCC.C=CCCCCCCCCCCCCCCCC.CCCCCCCCCCCCCCCCCC.O.O.O.O.[N+]([O-])([O-])=O.[Cd+2:66].[N+]([O-])([O-])=O.C(O)(=O)CCCCCCCCCCCCC.[N+]([O-])(O)=O.[OH-].[Na+]>C([O-])(=O)CCCCCCCCCCCCCCCCC.[Zn+2].C([O-])(=O)CCCCCCCCCCCCCCCCC.O.O.O.O.C([O-])(=O)C.[Mn+2].C([O-])(=O)C>[C:2]([O-:21])(=[O:20])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15].[Cd+2:66].[C:2]([O-:21])(=[O:20])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15]

参加物

11

反応物 8

HCID 944Nitric AcidHCID 82171-OctadeceneHCID 11005Myristic AcidHCID 11635OctadecaneHCID 14798Sodium HydroxideHCID 445639Oleic AcidHCID 5362487SulfurHCID 56924536Cadmium nitrate tetrahydrate

生成物 1

HCID 66290Tetradecanoic acid, cadmium salt (2:1)

試薬・触媒・溶媒 2

HCID 11178Zinc Stearate触媒HCID 93021Manganese acetate tetrahydrate触媒

実験手順

Sulfur powder (99.999%), oleic acid (OLA, 90%), 1-octadecene (ODE, 90%), octadecane (ODA, 99%), oleyamine (OAm, 70%), polystyrene-block-polybutadiene (C12H14, 30 wt % styrene, 80% diblock), cadmium nitrate tetrahydrate (Cd(NO3)2.4H2O, 99.99%), zinc stearate (count as ZnO %≈14%), myristic acid (MA, 99%), nitric acid (69.5%), manganese acetate tetrahydrate (99%), and sodium hydroxide (NaOH) were purchased from commercial sources and used as received without further purification. Cadmium myristate was synthesized according to a literature method.

後処理

  1. customas received without further purification

出典と根拠

ORDレコード
ord-7fa8d41e84da478380eeb966cde52733
出典データセット
uspto-grants-2013_04
特許番号
US08410455B2

関連ノート

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