m-Chloroperbenzoic acid → Pyridine, 2-[[(2-methylphenyl)methyl]sulfinyl]-, 1-oxide

HRID 2072255

反応式

HRID 2072255 の反応式
[CH3:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[CH2:8][S:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][N+:11]=1[O-:16].C1C=C(Cl)C=C(C(OO)=[O:25])C=1>C(Cl)(Cl)Cl>[CH3:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[CH2:8][S:9]([C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][N+:11]=1[O-:16])=[O:25]

参加物

4

反応物 2

HCID 70297m-Chloroperbenzoic acidHCID 456923522-(2-methylphenylmethylthio)pyridine N-oxide

生成物 1

HCID 501068Pyridine, 2-[[(2-methylphenyl)methyl]sulfinyl]-, 1-oxide

試薬・触媒・溶媒 1

HCID 6212Chloroform溶媒2 回

実験手順

To a vigorously stirred solution of 6.9 gm (0.03 mol) of 2-(2-methylphenylmethylthio)pyridine N-oxide in 50 ml of chloroform maintained at 0° to 10° C. is slowly added a solution of 6 gm (0.03 mol) MCPBA (85%) in 100 ml of chloroform. When addition is complete the temperature is allowed to rise to ambient. After sixteen hours the reaction solution is washed up in the manner described in Example 139.

後処理

  1. additionWhen addition
  2. washAfter sixteen hours the reaction solution is washed up in the manner

出典と根拠

ORDレコード
ord-e8ec416a33d04210a65bab9cac42d512
出典データセット
uspto-grants-1977_09
特許番号
US04050921

関連ノート

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