Ammonia → Triallylamine

HRID 2165976

反応式

HRID 2165976 の反応式
C1(P([C:25]2[CH:30]=[CH:29]C=CC=2)CCCCP(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.C(O)CCO.C(O)C=C.N.[CH2:41]([NH:44][CH2:45][CH:46]=[CH2:47])[CH:42]=[CH2:43]>Cl[Pd]Cl.O>[CH2:41]([NH2:44])[CH:42]=[CH2:43].[CH2:41]([N:44]([CH2:29][CH:30]=[CH2:25])[CH2:45][CH:46]=[CH2:47])[CH:42]=[CH2:43]

参加物

9

反応物 5

HCID 222AmmoniaHCID 7858Allyl AlcoholHCID 104421,3-PropanediolHCID 31279DiallylamineHCID 821241,4-Bis(diphenylphosphino)butane

生成物 2

HCID 7617TriallylamineHCID 7853Allylamine

試薬・触媒・溶媒 2

HCID 24290Palladium Chloride触媒HCID 962Water溶媒

実験手順

To 1.8 mg (0.01 millimole) of PdCl2 was added 8.5 mg (0.02 millimole) of 1,4-bis(diphenylphosphino)butane, and 5.0 g of 1,3-propane-diol, 3.6 mg of water and 9.1 mg (0.01 millimole) of tetramethyl hydroxide were added and reaction between 8.4 g (145 millimoles) of allyl alcohol and 4.6 g (271 millimoles) of ammonia was carried out at 110° C. with stirring for 2 hours. As the products, there were obtained 0.20 g (3.5 millimoles) of monoallylamine, 0.78 (8.0 millimoles) of diallylamine and 0.92 g (6.7 millimoles) of triallylamine. The conversion based on allyl alcohol was 29.8%, and the selectivity was 91.7%.

後処理

  1. additionwere added
  2. customwas carried out at 110° C.

出典と根拠

ORDレコード
ord-4ecc615556864fdabe3e64600d30a813
出典データセット
uspto-grants-1990_07
特許番号
US04942261

関連ノート

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