Ammonia → Triallylamine

HRID 2165977

反応式

HRID 2165977 の反応式
C(P(C[CH2:20][CH2:21][CH3:22])CCCCP(CCCC)CCCC)CCC.C(O)[CH2:24][CH2:25][CH2:26]O.[CH2:29](O)[CH:30]=[CH2:31].N.[CH2:34]([NH2:37])[CH:35]=[CH2:36]>>[CH2:34]([NH:37][CH2:20][CH:21]=[CH2:22])[CH:35]=[CH2:36].[CH2:29]([N:37]([CH2:34][CH:35]=[CH2:36])[CH2:24][CH:25]=[CH2:26])[CH:30]=[CH2:31]

参加物

7

反応物 5

HCID 222AmmoniaHCID 7853AllylamineHCID 7858Allyl AlcoholHCID 80641,4-ButanediolHCID 13415111(Butane-1,4-diyl)bis(dibutylphosphane)

生成物 2

HCID 7617TriallylamineHCID 31279Diallylamine

実験手順

To 12.2 mg (0.04 millimole) of Pd(CH2COCH2COCH3)2 was added 42.6 mg (0.10 millimole) of 1,4-bis(dibutylphosphino)butane, and 5.0 g of 1,4-butane-diol was added and reaction between 8.4 g (182 millimoles) of allyl alcohol and 3.1 g (182 millimoles) of ammonia was carried out at 120° C. for 2 hours with stirring. As the products, there were obtained 0.91 (16.0 millimoles) of monoallylamine, 1.85 g (19.1 millimoles) of diallylamine and 2.35 g (17.2 millimoles) of triallylamine. The conversion based on allylalcohol was 74.3%, and the selectivity was 98.2%.

後処理

  1. additionwas added

出典と根拠

ORDレコード
ord-9dc78c9411d54f8191a39404f11287cc
出典データセット
uspto-grants-1990_07
特許番号
US04942261

関連ノート

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