Ethanol → HCID 20498860、化合物

HRID 2166733ノート

反応式

HRID 2166733 の反応式
[CH2:1]([OH:7])/[CH:2]=[CH:3]/[CH:4]=[CH:5]/[CH3:6].[Li].[CH3:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14].C(O)C>C1COCC1>[CH2:1]([O:7][CH2:9]/[CH:10]=[CH:11]/[CH:12]=[CH:13]/[CH3:14])/[CH:2]=[CH:3]/[CH:4]=[CH:5]/[CH3:6]

参加物

6

反応物 4

HCID 702EthanolHCID 8058HexaneHCID 641256trans,trans-2,4-Hexadien-1-olHCID 3028194Lithium

生成物 1

HCID 20498860HCID 20498860、化合物

試薬・触媒・溶媒 1

HCID 8028Tetrahydrofuran溶媒

実験手順

A mixture of 10 g of the polymer from Example 17, 2.2 ml of sorbyl alcohol (2,4-hexadienol) and 0.1 g of lithium metal in 100 ml of THF was refluxed under nitrogen for 18 hours. The mixture was then cooled and a 10-ml portion was poured into 100 ml of hexane containing 2 ml of ethanol to obtain the solid product. To further purify, it was redissolved in 10 ml of THF and suction filtered through a fine frit into 100 ml of water. The precipitated solid was collected and dried.

後処理

  1. temperaturewas refluxed under nitrogen for 18 hours
  2. temperatureThe mixture was then cooled
  3. customto obtain the solid product
  4. customTo further purify
  5. dissolutionit was redissolved in 10 ml of THF
  6. filtrationsuction filtered through a fine frit into 100 ml of water
  7. customThe precipitated solid was collected
  8. customdried

出典と根拠

ORDレコード
ord-40c19d5a3dd04f2c8d0a64cf7f14986d
出典データセット
uspto-grants-1983_06
特許番号
US04388448

反応ノート

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