Hydrochloric Acid → 2-Propenoic acid, 3-phenyl-

HRID 22092

反応式

HRID 22092 の反応式
O[C:2]1[CH:12]=[CH:11][C:5]([CH:6]=[CH:7][C:8]([OH:10])=[O:9])=[CH:4][CH:3]=1.[OH-].[K+].N#N.C1OC1CO.Cl>CS(C)=O.OCC(CO)O>[C:8]([OH:10])(=[O:9])[CH:7]=[CH:6][C:5]1[CH:4]=[CH:3][CH:2]=[CH:12][CH:11]=1

参加物

8

反応物 5

HCID 313Hydrochloric AcidHCID 3224-Coumaric acidHCID 947NitrogenHCID 11164GlycidolHCID 14797Potassium Hydroxide

生成物 1

HCID 87842-Propenoic acid, 3-phenyl-

試薬・触媒・溶媒 2

HCID 679Dimethyl Sulfoxide溶媒HCID 753Glycerol溶媒

実験手順

4.35 g of p-hydroxy cinnamic acid was dissolved in 5 ml of DMSO, and 50 mg of potassium hydroxide was added. The mixture was stirred and heated to 90° C. under flow of N2 gas. 10.0 g of glycidol was added gradually, heating and agitation was carried out for 1.5 hours, neutralized by adding hydrochloric acid and the adduct of cinnamic acid and glycerin was obtained.

後処理

  1. temperatureheating

出典と根拠

ORDレコード
ord-542a9da6771c4edf9109f3992e977503
出典データセット
uspto-grants-1995_06
特許番号
US05426210

関連ノート

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