m-Chloroperbenzoic acid → 3-methylsulfinyl-N'-sulfamoylpropanimidamide

HRID 2413345

反応式

HRID 2413345 の反応式
ClC1C=CC=C(C(OO)=[O:9])C=1.[S:12]([NH:16][C:17](=[NH:22])[CH2:18][CH2:19][S:20][CH3:21])(=[O:15])(=[O:14])[NH2:13]>C(Cl)(Cl)Cl.CO>[S:12]([NH:16][C:17](=[NH:22])[CH2:18][CH2:19][S:20]([CH3:21])=[O:9])(=[O:14])(=[O:15])[NH2:13]

参加物

5

反応物 2

HCID 70297m-Chloroperbenzoic acidHCID 178503794HCID 178503794、化合物

生成物 1

HCID 1785046403-methylsulfinyl-N'-sulfamoylpropanimidamide

試薬・触媒・溶媒 2

HCID 887Methanol溶媒HCID 6212Chloroform溶媒

実験手順

A solution of commercial 80% pure m-chloroperbenzoic acid (5.4 g, 25 mmol) in chloroform (40 ml) was added dropwise to a solution of N-sulfamyl-3-(methylthio)propionamidine (4.94 g, 25 mmol) in methanol (50 ml) at room temperature. After stirring for two hours, the product was collected by filtration, analytically pure, to give 4.44 g, mp 141°-144°.

後処理

  1. filtrationthe product was collected by filtration
  2. customanalytically pure, to give 4.44 g, mp 141°-144°

出典と根拠

ORDレコード
ord-461e854f44064aca83215e2c4ef6b828
出典データセット
uspto-grants-1985_01
特許番号
US04496737

関連ノート

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