Bis(eta-cyclopentadienyl) iron → Bis(eta-cyclopentadienyl) iron

HRID 249569

反応式

HRID 249569 の反応式
Cl[Sn]Cl.[Cl:4][CH2:5][CH2:6][CH2:7][C:8]([C-:10]1[CH:14]=[CH:13][CH:12]=[CH:11]1)=[O:9].[CH-:15]1[CH:19]=[CH:18][CH:17]=[CH:16]1.[Fe+2:20].[CH-:21]1[CH:25]=[CH:24][CH:23]=[CH:22]1.[CH-:26]1[CH:30]=[CH:29][CH:28]=[CH:27]1.[Fe+2].[Cl:32][CH2:33][CH2:34][CH2:35][C:36]([C-]1C=CC=C1)=[O:37].[C-]1(C(=O)CCC[Cl:52])C=CC=C1.[Fe+2]>C(Cl)Cl.[Al+3].[Cl-].[Cl-].[Cl-].O=[Pt]=O.C(O)(=O)C>[Cl:4][CH2:5][CH2:6][CH2:7][C:8]([C-:10]1[CH:14]=[CH:13][CH:12]=[CH:11]1)=[O:9].[CH-:15]1[CH:19]=[CH:18][CH:17]=[CH:16]1.[Fe+2:20].[CH-:21]1[CH:25]=[CH:24][CH:23]=[CH:22]1.[CH-:26]1[CH:30]=[CH:29][CH:28]=[CH:27]1.[Fe+2:20].[Cl:32][CH2:33][CH2:34][CH2:35][C:36]([Cl:52])=[O:37]

参加物

11

反応物 4

HCID 7611Bis(eta-cyclopentadienyl) ironHCID 24479Stannous ChlorideHCID 178520619HCID 178520619、化合物HCID 178520620HCID 178520620、化合物

生成物 3

HCID 7611Bis(eta-cyclopentadienyl) ironHCID 783704-Chlorobutyryl chlorideHCID 178520619HCID 178520619、化合物

試薬・触媒・溶媒 4

HCID 345198Adams' catalyst触媒HCID 6451240Aluminum(III) Chloride触媒HCID 176Acetic Acid溶媒HCID 6344Dichloromethane溶媒

実験手順

In an inert atmosphere, 170 mg of PtO2.xH2O (containing 80% of Pt) and 5 mg of anhydrous SnCl2 are introduced into the glass beaker. 120 cm3 of glacial acetic acid and 29.1 g (0.10 mol) of 4-chlorobutyroylferrocene whose main impurities are 1.4% by weight of ferrocene and 0.88% by weight of 1,1'-di(4-chlorobutyroyl)ferrocene are then poured in. This 4-chlorobutyroylferrocene was obtained in the customary manner by a reaction of the Friedel-Crafts type between ferrocene and 4-chlorobutyryl chloride in CH2Cl2 in the presence of AlCl3 as catalyst, followed by recrystallisation of the crude product obtained from hexane.

後処理

  1. additionare introduced into the glass beaker
  2. additionare then poured in

出典と根拠

ORDレコード
ord-7535c6cada5e4d8aa4c298bdb54a4fc2
出典データセット
uspto-grants-1993_05
特許番号
US05214175

関連ノート

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