Sulfuric Acid → Catechol

HRID 256136

反応式

HRID 256136 の反応式
S(=O)(=O)(O)O.[As].[CH2:7]([C:13]1[CH:19]=[CH:18][CH:17]=[C:15]([OH:16])[C:14]=1[OH:20])[CH2:8][CH2:9][CH2:10][CH2:11]C>[Cu]>[CH2:13]=[CH:7][CH2:8][CH2:9][CH2:10][CH3:11].[C:15]1([C:14](=[CH:13][CH:19]=[CH:18][CH:17]=1)[OH:20])[OH:16]

参加物

6

反応物 3

HCID 1118Sulfuric AcidHCID 5359596ArsenicHCID 19900938n-Hexylpyrocatechol

生成物 2

HCID 289CatecholHCID 115971-Hexene

試薬・触媒・溶媒 1

HCID 23978Copper触媒

実験手順

100 ml of an aqueous solution containing sulfuric acid (200 g/l), copper (45 g/l) and arsenic (5.9 g/l) were poured into a 250 ml separatory funnel. Then a 0.3M solution of n-hexylpyrocatechol (100 ml), (a mixture of the two position isomers obtained from the reaction of 1-hexene with excess of pyrocatechol), was added into ESCAID 100; the mixture was strongly stirred for 10' and made then to settle for 30'.

後処理

  1. additionwere poured into a 250 ml separatory funnel

出典と根拠

ORDレコード
ord-7f93ba93cc1a4198905453e2317ded0e
出典データセット
uspto-grants-1987_10
特許番号
US04701311

関連ノート

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