1-Butanol → 2-Hydroxydecyl-butyl ether

HRID 267607

反応式

HRID 267607 の反応式
[O:1]1[CH:3]([CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:2]1.[Na].C1OC1.[CH2:16]([OH:20])[CH2:17][CH2:18][CH3:19]>C[O-].[Na+]>[OH:1][CH:3]([CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:2][O:20][CH2:16][CH2:17][CH2:18][CH3:19]

参加物

6

反応物 4

HCID 2631-ButanolHCID 6354Ethylene OxideHCID 169931,2-EpoxydecaneHCID 5360545Sodium

生成物 1

HCID 104664152-Hydroxydecyl-butyl ether

試薬・触媒・溶媒 1

HCID 10942334Sodium Methoxide触媒

実験手順

As described in Example 1, 1 mol of 1,2-epoxydecane was caused to react with 5 times the molar quantity of n-butanol and 0.04 gm-atom of sodium. After distillation of the excess alcohol, the reaction with 10 mols of ethylene oxide was conducted in an autoclave under the conditions described in Example 1, except for the addition of the sodium methylate catalyst. The product thus obtained had a cloud point of 64°C.

後処理

  1. distillationAfter distillation of the excess alcohol
  2. customThe product thus obtained

出典と根拠

ORDレコード
ord-5d32d71825f34bd8a73662fac1561a93
出典データセット
uspto-grants-1976_03
特許番号
US03943178

関連ノート

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