Methane → Cyclohexyl isocyanate

HRID 279797

反応式

HRID 279797 の反応式
[CH:1]1([NH2:7])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[C:8]1([OH:18])C2C(=CC=CC=2)C=CC=1.C>[I-].C([N+](CC)(CC)CC)C.[Rh]>[CH:1]1([N:7]=[C:8]=[O:18])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1

参加物

6

反応物 3

HCID 297MethaneHCID 70051-NaphtholHCID 7965Cyclohexylamine

生成物 1

HCID 18502Cyclohexyl isocyanate

試薬・触媒・溶媒 2

HCID 6225Tetraethylammonium Iodide触媒HCID 23948Rhodium触媒

実験手順

The carbonylation reaction is conducted in the same manner as in Example 1 except that 25 mmol of cyclohexylamine, 86 g of α-naphthol, 1.5 g of Rh/C having 5% Rh carried on activated charcoal and 1 mmol of tetraethylammonium iodide are employed. As a result, the yields of cyclohexyl isocyanate and α-naphthyl cyclohexyl carbamate are 58% and 10%, respectively.

後処理

  1. customThe carbonylation reaction

出典と根拠

ORDレコード
ord-df5d85d8c97f4f9bbfa76d696c7c7942
出典データセット
uspto-grants-1986_05
特許番号
US04587056

関連ノート

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