Hydrogen Peroxide → Perbenzoic acid
反応式
Cl[C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([C:8]([O:10][OH:11])=[O:9])[CH:3]=1.B([O-])([O-])[O-].[Na+].[Na+].[Na+].FC(F)(F)C(O)=O.C(OC(=O)C)(=O)C.OO>>[CH:3]1[C:4]([C:8]([O:10][OH:11])=[O:9])=[CH:5][CH:6]=[CH:7][CH:2]=1参加物
6
実験手順
m-Chloroperbenzoic acid (MCPBA), a mixture of sodium borate and trifluoroacetic acid or a mixture of acetic anhydride and H2O2 is preferably used for the oxidation. If desired, a commercially available wetting agent can additionally be added to the oxidizing agent. The reaction times lie in a wide range and range from about 0.5 to about 15 hours, preferably 1 to 8 hours. The reaction temperature ranges from −20 to about 100° C., preferably from 0 to about 85° C.
後処理
- additiona commercially available wetting agent can additionally be added to the oxidizing agent
- customThe reaction times
- customranges from −20 to about 100° C., preferably from 0 to about 85° C.
出典と根拠
- ORDレコード
- ord-cf42e1c3c252406f96f3ed982b503b07
- 出典データセット
- uspto-grants-2001_04
- 特許番号
- US06215029B1
反応ノート
読み込み中…