Acrylic Acid → Prop-2-enoic acid--prop-2-enal (1/1)

HRID 37736

反応式

HRID 37736 の反応式
[C:1]([OH:5])(=[O:4])[CH:2]=[CH2:3].C(C=C)=O>CO>[CH:1]([CH:2]=[CH2:3])=[O:4].[C:1]([OH:5])(=[O:4])[CH:2]=[CH2:3]

参加物

4

反応物 2

HCID 6581Acrylic Acid2 回HCID 7847Acrolein2 回

生成物 1

HCID 3084492Prop-2-enoic acid--prop-2-enal (1/1)

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

Control drug: (acrylic acid:acrolein (mol)=90:10): 7.04 g freshly distilled acrolein and 81.43 g freshly distilled acrylic acid were added into a three-port flask with 530 ml absolute methanol, purged with nitrogen, 5.47 g benzoyl peroxide was added, and the solution was stirred and heated to reflux under nitrogen for 50 h. The reaction solution became a yellowish viscous liquid, which was dried under vacuum at 50-100° C. for 24 hours to form poly (acrolein-acrylic acid) named A5.

後処理

  1. custompurged with nitrogen, 5.47 g benzoyl peroxide
  2. additionwas added
  3. temperatureheated
  4. temperatureto reflux under nitrogen for 50 h
  5. customwas dried under vacuum at 50-100° C. for 24 hours

出典と根拠

ORDレコード
ord-6f1d96f9b6954f10a11099f21711a51e
出典データセット
uspto-grants-2013_09
特許番号
US08524216B2

関連ノート

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