Methyl Chloride → CHCl2CF2CHFCF3

HRID 41730

反応式

HRID 41730 の反応式
C[Cl:2].CF.C(F)F.[CH:8]([Cl:11])(F)F.[F:12][C:13]([F:20])([F:19])[C:14]([F:18])=[C:15]([F:17])[F:16].FF>C(Cl)Cl.C(Cl)(Cl)(Cl)Cl.C(Cl)(Cl)Cl>[CH:8]([C:15]([CH:14]([C:13]([F:20])([F:19])[F:12])[F:18])([F:17])[F:16])([Cl:11])[Cl:2]

参加物

10

反応物 6

HCID 6327Methyl ChlorideHCID 6345DifluoromethaneHCID 6372ChlorodifluoromethaneHCID 8302Hexafluoropropylene2 回HCID 11638FluoromethaneHCID 24524Fluorine

生成物 1

HCID 12829383CHCl2CF2CHFCF3収率 85%

試薬・触媒・溶媒 3

HCID 5943Carbon Tetrachloride溶媒HCID 6212Chloroform溶媒HCID 6344Dichloromethane溶媒2 回

実験手順

Typical compounds conforming to the above general formula are CH3Cl, CH2Cl2, CHCl3, CCl4, CH3F, CH2F2, CHF2Cl, and the like. Addition of such compounds to hexafluoropropene thermally is described in J. Fluorine Chemistry 1982, 21, 253-259. For example, CH2Cl2 addition to CF3CF═CF2 at 280° C. is reported to give 85% yield of CHCl2CF2CHFCF3.

後処理

  1. customat 280° C.

出典と根拠

ORDレコード
ord-f46cd7262d8d4f379ae685c22bb11190
出典データセット
uspto-grants-2013_09
特許番号
US08530709B2

関連ノート

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