Phenyl Salicylate → 2'-Ethyl-salicylanilide

反応式

[C:1]([O:10]C1C=CC=CC=1)(=O)[C:2]1[C:3](=[CH:5][CH:6]=[CH:7][CH:8]=1)[OH:4].[CH2:17]([C:19]1[CH:25]=[CH:24][CH:23]=[CH:22][C:20]=1[NH2:21])[CH3:18]>>[CH2:17]([C:19]1[CH:25]=[CH:24][CH:23]=[CH:22][C:20]=1[NH:21][C:1](=[O:10])[C:2]1[C:3](=[CH:5][CH:6]=[CH:7][CH:8]=1)[OH:4])[CH3:18]

参加物

反応物 2

HCID 8361Phenyl Salicylate

HCID 113572-Ethylaniline

生成物 1

HCID 187609142'-Ethyl-salicylanilide

実験手順

The 2′-ethyl-salicylanilide was prepared by condensing phenyl salicylate with 2-ethylaniline then purified as described in Example 2a. The ligand mixture was then prepared from 2′-ethyl-salicylanilide and 1,1′-bi-2-naphthol using the procedure described in Example 2a. 31P NMR (121.77 MHz): several peaks between 117.1-118.8 ppm.

後処理

customthen purified
customThe ligand mixture was then prepared from 2′-ethyl-salicylanilide and 1,1′-bi-2-naphthol using the procedure

出典と根拠

ORDレコード: ord-4bbf13c0bf514f11b9c4464537d267e6
出典データセット: uspto-grants-2003_12
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US06664427B1

反応ノート

読み込み中…

参加物