Hydroxyacetone → 2-Propanone, 1-((methylsulfonyl)oxy)-

HRID 47531

反応式

HRID 47531 の反応式
[OH:1][CH2:2][C:3](=[O:5])[CH3:4].[CH3:6][S:7](Cl)(=[O:9])=[O:8].C(=O)(O)[O-].[Na+]>C(Cl)(Cl)Cl>[CH3:6][S:7]([O:1][CH2:2][C:3]([CH3:4])=[O:5])(=[O:9])=[O:8]

参加物

5

反応物 3

HCID 8299HydroxyacetoneHCID 31297Methanesulfonyl chlorideHCID 516892Sodium Bicarbonate

生成物 1

HCID 1467542-Propanone, 1-((methylsulfonyl)oxy)-

試薬・触媒・溶媒 1

HCID 6212Chloroform溶媒

実験手順

Thirty-seven (37) mg of hydroxyacetone was dissolved in 2 ml of chloroform, and to which 0.078 ml of methanesulfonyl chloride was added. After stirring the reaction liquid at room temperature for 30 minutes, saturated aqueous sodium bicarbonate solution was added and extracted with chloroform. The extract was dried over anhydrous sodium sulfate and concentrated to provide the title compound.

後処理

  1. customthe reaction liquid at room temperature for 30 minutes
  2. extractionextracted with chloroform
  3. dry with materialThe extract was dried over anhydrous sodium sulfate
  4. concentrationconcentrated

出典と根拠

ORDレコード
ord-ae0dc196daec479296ba40aa26395f87
出典データセット
uspto-grants-2004_03
特許番号
US06699880B1

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