Ammonia → N,N-Diethylaniline

HRID 476305

反応式

HRID 476305 の反応式
[NH3:1].[BH3:2].[CH2:3]([N:5]([CH2:12][CH3:13])[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)[CH3:4].B.[C:15]1([N:21]2[CH2:26][CH2:25][O:24][CH2:23][CH2:22]2)[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1.B.[N:28]1[C:33]([CH3:34])=[CH:32][CH:31]=[CH:30][C:29]=1[CH3:35]>>[CH3:13][CH2:12][N:5]([C:6]1[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=1)[CH2:3][CH3:4].[C:15]1([N:21]2[CH2:26][CH2:25][O:24][CH2:23][CH2:22]2)[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1.[N:28]1[C:33]([CH3:34])=[CH:32][CH:31]=[CH:30][C:29]=1[CH3:35].[NH3:1].[BH3:2]

参加物

8

反応物 4

HCID 222Ammonia2 回HCID 83312Diethylaniline-boraneHCID 15265529(T-4)-Trihydro(4-phenylmorpholine-kappaN4)boronHCID 178419164HCID 178419164、化合物

生成物 4

HCID 7061N,N-DiethylanilineHCID 79372,6-LutidineHCID 623394-PhenylmorpholineHCID 419330Ammonia;borane

実験手順

For example, dimethylaniline borane can be reacted with ammonia to produce ammonia borane as shown below. (C6H5)(CH3)2N.BH3+NH3═(C6H5)(CH3)2N+NH3.BH3 In other examples, diethylaniline borane, phenylmorpholine borane or lutidine borane can be reacted with ammonia to form diethylaniline and ammonia borane, phenylmorpholine and ammonia borane, or lutidine and ammonia borane.

出典と根拠

ORDレコード
ord-0a3d2fda4d6b4e7f9b7c1dc15d2c5642
出典データセット
uspto-grants-2014_01
特許番号
US08637703B2

関連ノート

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