Glycidyl acrylate → HCID 86655545、化合物

HRID 574026

反応式

HRID 574026 の反応式
[C:1]([O:5][CH2:6][CH:7]1[O:9][CH2:8]1)(=[O:4])[CH:2]=[CH2:3].[C:10]([O:15][CH2:16][CH2:17][OH:18])(=[O:14])[C:11]([CH3:13])=[CH2:12].[C:19]([O:22][C:23]1[CH:30]=[CH:29][C:26]([CH:27]=[CH2:28])=[CH:25][CH:24]=1)(=[O:21])[CH3:20].N(C(C)(CC)C([O-])=O)=NC(C)(CC)C([O-])=O>CCCCCCC.C(C(C)=O)C(C)C>[C:1]([O:5][CH2:6][CH:7]1[O:9][CH2:8]1)(=[O:4])[CH:2]=[CH2:3].[C:10]([O:15][CH2:16][CH2:17][OH:18])(=[O:14])[C:11]([CH3:13])=[CH2:12].[C:19]([O:22][C:23]1[CH:30]=[CH:29][C:26]([CH:27]=[CH2:28])=[CH:25][CH:24]=1)(=[O:21])[CH3:20]

参加物

7

反応物 4

HCID 7836Glycidyl acrylateHCID 133602-Hydroxyethyl MethacrylateHCID 758214-Ethenylphenyl acetateHCID 219175032,2'-Azobis(methyl 2-methylpropanate)

生成物 1

HCID 86655545HCID 86655545、化合物

試薬・触媒・溶媒 2

HCID 7909Methyl Isobutyl Ketone溶媒HCID 8900Heptane溶媒

実験手順

Into a 500 ml-volume three-neck flask, 46.1 g (0.36 mol) of glycidyl acrylate, 15.6 g (0.12 mol) of 2-hydroxyethyl methacrylate, 19.5 g (0.12 mol) of p-acetoxystyrene and 300 ml of methyl isobutyl ketone were charged. A catalytic amount of 2,2′-azobis(methyl 2-methylpropionate) was added thereto as a radical polymerization initiator, and polymerization was allowed to proceed at 80° C. for 6 hours in a nitrogen stream. The reaction solution was cooled and then poured in a large amount of heptane to precipitate a polymer. The crystal was collected by filtration and dissolved in diethylene glycol dimethyl ether, and heptane and methyl isobutyl ketone contained in the solution were removed by distillation under reduced pressure to obtain Polymer A2-2 (glycidyl acrylate/2-hydroxyethyl methacrylate/p-acetoxystyrene) as a diethylene glycol dimethyl ether solution.

後処理

  1. customas a radical polymerization initiator, and polymerization
  2. temperatureThe reaction solution was cooled
  3. customto precipitate a polymer
  4. filtrationThe crystal was collected by filtration
  5. dissolutiondissolved in diethylene glycol dimethyl ether
  6. customwere removed by distillation under reduced pressure

出典と根拠

ORDレコード
ord-07cc3b10779746bcb3093aa6e64a7431
出典データセット
uspto-grants-2015_05
特許番号
US09034440B2

関連ノート

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