Bromomethyl 4-methoxyphenyl ketone → N-(4-chlorophenacyl) pyridazinium chloride

HRID 596723

反応式

HRID 596723 の反応式
[N:1]1[CH:6]=[CH:5][CH:4]=[CH:3][N:2]=1.COC1C=CC(C(=O)CBr)=CC=1.[Cl:19][C:20]1[CH:29]=[CH:28][C:23]([C:24](=[O:27])[CH2:25]Cl)=[CH:22][CH:21]=1>N1C=CC=CC=1>[Cl-:19].[Cl:19][C:20]1[CH:29]=[CH:28][C:23]([C:24](=[O:27])[CH2:25][N+:1]2[CH:6]=[CH:5][CH:4]=[CH:3][N:2]=2)=[CH:22][CH:21]=1

参加物

5

反応物 3

HCID 4965Bromomethyl 4-methoxyphenyl ketoneHCID 9259PyridazineHCID 702982,4'-Dichloroacetophenone

生成物 1

HCID 86734540N-(4-chlorophenacyl) pyridazinium chloride

試薬・触媒・溶媒 1

HCID 1049Pyridine溶媒

実験手順

Employing the procedure of Example I but replacing pyridine with a substantially equimolecular amount of pyridazine and replacing 4-methoxyphenacyl bromide with a substantially equimolecular amount of 4-chlorophenacyl chloride there is obtained N-(4-chlorophenacyl) pyridazinium chloride, a solid soluble in water.

出典と根拠

ORDレコード
ord-6e87b6dd681d4db6920a8772c4d5d4ea
出典データセット
uspto-grants-1977_03
特許番号
USRE029153

関連ノート

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