Antioxidant 1010 → Allyl methacrylate

HRID 620691

反応式

HRID 620691 の反応式
[C:1]([O-:6])(=[O:5])[C:2]([CH3:4])=[CH2:3].[CH3:7][CH2:8][CH2:9]C[N+](CCCC)(CCCC)CCCC.[F-].CC(C1C(O)=C(C(C)(C)C)C=C(CCC(OCC(COC(CCC2C=C(C(C)(C)C)C(O)=C(C(C)(C)C)C=2)=O)(COC(CCC2C=C(C(C)(C)C)C(O)=C(C(C)(C)C)C=2)=O)COC(CCC2C=C(C(C)(C)C)C(O)=C(C(C)(C)C)C=2)=O)=O)C=1)(C)C>C1COCC1>[C:1]([O:6][CH2:9][CH:8]=[CH2:7])(=[O:5])[C:2]([CH3:4])=[CH2:3]

参加物

5

反応物 3

HCID 64819Antioxidant 1010HCID 87595MethacrylateHCID 2724141Tetrabutylammonium Fluoride

生成物 1

HCID 7274Allyl methacrylate

試薬・触媒・溶媒 1

HCID 8028Tetrahydrofuran溶媒

実験手順

To a stirred solution of MTS (5.5×10-3 g) in dry THF (10.0 ml) was added (D2.1) (3.0 g), AM (0.11 ml) and TBAF (2 μ1 of 1M THF solution). The mixture warmed up and was stirred overnight at room temperature. 50 ppm Irganox 1010 antioxidant was added to the very viscous clear solution, which was cast into a polyester tray in a stream of nitrogen. The last traces of THF were removed by heating in a vacuum oven at 60° for 4 hours.

後処理

  1. temperatureThe mixture warmed up
  2. customThe last traces of THF were removed
  3. temperatureby heating in a vacuum oven at 60° for 4 hours

出典と根拠

ORDレコード
ord-b384d9273fd6413d90ef7092d73a8ce7
出典データセット
uspto-grants-1989_04
特許番号
US04822701

関連ノート

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