Bis(eta-cyclopentadienyl) iron → Mesitylene
反応式
[CH-:1]1[CH:5]=[CH:4][CH:3]=[CH:2]1.[CH-]1C=CC=C1.[Fe+2:11].[Al+3].[Cl-].[Cl-].[Cl-].[C:16]1([CH3:24])[CH:21]=[C:20]([CH3:22])[CH:19]=[C:18]([CH3:23])[CH:17]=1>[Cl-].[Cl-].[Cl-].[Cl-].[Zr+4]>[C:16]1([CH3:24])[CH:21]=[C:20]([CH3:22])[CH:19]=[C:18]([CH3:23])[CH:17]=1.[CH:1]1([Fe+:11])[CH:5]=[CH:4][CH:3]=[CH:2]1参加物
6
実験手順
In accordance with the procedure of Example 4, 10 g (0.043 mol) of ZrCl4 are added at 60° C. under argon over the course of 1 hour and 10 minutes to a stirred mixture of 60 ml of mesitylene, 8 g (0.043 mol) of ferrocene and 5.7 g (0.043 mol) of sublimed AlCl3. Working up is effected as in Example 4, affording 20.1 g (83.4% of theory) of crude (η6 -mesitylene)-η5 -(cyclopentadienyl)-iron(II) tetrapnenylborate.
出典と根拠
- ORDレコード
- ord-6e509896da094dc58fef5e22f2f94349
- 出典データセット
- uspto-grants-1993_09
- 特許番号
- US05247107
反応ノート
読み込み中…